A Stable and Photoreactive Copper‐Iodide Cubane Suitable for Direct Post‐Functionalization
نویسندگان
چکیده
Tetranuclear copper-iodide cluster consisting of a {Cu4I4} cubane and diphenylphosphine ligand has been found as highly stable precursor for further post-functionalization through hydrophosphination reaction. UV irradiation the in presence various alkenes allows direct functionalization latter, giving access to wide range copper complexes, source molecular diversity luminescent materials. Such strategy provided first example water-soluble iodide.
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ژورنال
عنوان ژورنال: European Journal of Inorganic Chemistry
سال: 2022
ISSN: ['1434-1948', '1099-0682']
DOI: https://doi.org/10.1002/ejic.202200101